The American Society for Testing and Materials
(ASTM) recognized oxo-biodegradation and ASTM D6954-04 is the
standard guide developed for Exposing and Testing plastics that
Degrade in the Environment by a Combination of Oxidation and
Biodegradation.
Unfortunately, however, at the present time there
are no standards available for the performance of degradable
and biodegradable plastics in other disposal environment other
than composting.
Commonly quoted standards for compostable plastics
are ASTM D6400-04 and EN 13432 and are related to the performance
of plastics in a commercially managed compost environment and
are not biodegradation standards. Both standards were developed
for hydro-biodegradable polymers (e.g. aliphatic polyesters
plus modified starch) where the mechanism inducing biodegradation
is based on reaction with water and state that in order for
a product to be compostable, the following criteria need to
be met:
1. Disintegration, the ability to fragment into
non-distinguishable pieces after screening and safely support
bio-assimilation and microbial growth;
2. Inherent Biodegradation, conversion of carbon
to carbon dioxide to the level of 60% and 90% over a period
of 180 days for ASTM D6400 and EN 13432 respectively
3. Safety, that there is no evidence of any eco-toxicity
in finished compost and soils can support plant growth; and
4. Toxicity, that heavy metal concentrations are
less than 50% regulated values in soil amendments.
Our oxo-biodegradable additives meet the requirements
of compostability outlined in these standards, except for the
rapid carbon to carbon dioxide conversion rate. Plastics made
with our additive degrade and ultimately biodegrade slower
than the rate specified in these standards. This does not mean
that they will not biodegrade; they just convert the carbon
to carbon dioxide in a slightly longer time frame. Many naturally
occurring materials, all biodegradable, do not convert in the
time frames established by ASTM D 6400-04 and EN 13432. To date,
we have been unsuccessful in making the point at these standards
organizations that the metrics of these standards are inconsistent
with the stated objective - to ensure that plastics entering
managed compost facilities biodegrade "at a rate comparable
to known compostable materials."
-biodegradable technology is not the ultimate
or only solution to problems related to plastic waste in the
environment but it is a step in the right direction.
There are several areas where oxo-biodegradable
plastics can have a major beneficial impact on the environment:
1 RECYCLING
Oxo-biodegradable plastic can be made from recyclate.
Oxo-biodegradable plastics can be recycled with other clean
commercial polyolefin wastes, provided that regard is had to
the inclusion rate and the level of degradation, and that stabilisers
are added where necessary.
2. LITTER
Policymakers need always to consider what happens
to waste plastic products which escape collection and end up
as litter. Discarded conventional plastics remain in the environment
for many decades, and are often impossible or too expensive
to collect, so recycling, landfill, composting, and incineration
are not options for dealing with them. If collected, oxo-biodegradable
plastics can be recycled or incinerated, and if not collected
they will degrade and disappear, leaving no harmful residues.
Exposure to sunlight accelerates degradation, but the process
of oxo-biodegradation, once initiated, continues even in the
absence of light, so long as air is present. The plastic will
degrade much more quickly in the open than in a building, and
in warm weather will disappear more quickly. Of course, if the
product has been exposed to air for some time before being discarded
it will disappear in an even shorter time thereafter.
3 LANDFILL
While disposal is at the bottom of the waste hierarchy,
the least desirable way of dealing with once used resources,
it remains the most commonly practiced way in virtually every
country in the world, including the most developed ones. Oxo-biodegradable
plastics fragment and partially biodegrade to CO2 and water
in the surface layers of the landfill, but the residues are
completely inert deeper in the landfill in the absence of oxygen.
They do not emit methane. Governments are concerned to reduce
the amount of waste going to landfill, but oxo-biodegradable
plastic waste does not have to be sent to landfill at all. It
can be recycled (see above). The aim of the EU Landfill Directive
1999 (as amended 2003) is that: (3) the prevention, recycling
and recovery of waste should be encouraged as should the use
of recovered materials and energy so as to safeguard natural
resources and obviate wasteful use of land; Oxo-biodegradable
plastics would help to achieve these objectives because, they
can be recycled and they can be incinerated with high energy-recovery.
Oxo-biodegradable plastic sheet would also reduce the wasteful
use of land in a landfill. At present a six to eight inch layer
of earth has to be spread over the waste at the end of each
day's work. This is very expensive to do, and it uses up a high
proportion of the available space in the landfill pit. Conventional
plastic products take up more space in a landfill because they
trap air, they do not readily disintegrate, and they inhibit
the decomposition of their contents in the landfill. (12) protective
measures [should] be taken against any threat to the environment
in the short as well as in the long-term perspective, and more
especially against the pollution of groundwater by leachate
infiltration into the soil. Oxo-biodegradable plastics do not
cause leachate infiltration (16) measures should be taken to
reduce the production of methane gas from landfills, inter alia,
in order to reduce global warming, through the reduction of
the landfill of biodegradable waste and the requirements to
introduce landfill gas control; Unlike normal organic waste,
oxo-biodegradable plastics do not produce methane as they degrade.
4. COMPOSTING
Certain standards exist for plastics to be designated
as compostable. Our oxo-biodegradable products do not meet
these standards, primarily because they do not biodegrade quickly
enough in a compost environment. Nonetheless, operators of a
number of managed compost facilities accept plastics using oxo-biodegradable
technology as an affordable alternative to generally more expensive
technologies that meet the standard requirements. Oxo-biodegradable
plastic products, do not biodegrade quickly enough to meet compostable
plastics standards, however this can be an advantage as they
sequester carbon in the soil and contribute to soil structure
and fertility producing high quality compost. The 11th September
2003 Report to the Australian Government by the Nolan-ITU Consultancy
concludes that: "oxo-biodegradable plastics based on polyolefins
contribute to the amount and nutritive value of the compost
because much of the carbon from the plastic is in the form of
intermediate oxidation products, humic material and cell biomass.
Oxo-biodegradable plastic does not degrade quickly in low temperature
"windrow" composting, but it is ideal for "in-vessel" composting
at the higher temperatures required by the new EU animal by-products
regulations. Indeed it is likely that windrow composting will
soon have to be phased out.
Because this is an additive technology that is applied to
conventional plastic resins, it complements rather than compromises
management strategies that are higher in the waste hierarchy: